Grain boundary melting in ice

Grain boundary melting in ice.

We describe an optical scattering study of grain boundary premelting in water ice. Ubiquitous long ranged attractive polarization forces act to suppress grain boundary melting whereas repulsive forces originating in screened Coulomb interactions and classical colligative effects enhance it. The liquid enhancing effects can be manipulated by adding dopant ions to the system. For all measured gra...

Abrupt grain boundary melting in ice.

The effect of impurities on the grain boundary melting of ice is investigated through an extension of Derjaguin-Landau-Verwey-Overbeek theory, in which we include retarded potential effects in a calculation of the full frequency-dependent van der Waals and Coulombic interactions within a grain boundary. At high dopant concentrations, the classical solutal effect dominates the melting behavior. ...

Grain Boundary Sliding in Ice

It is well known that grain boundary processes intercrystdline sliding and grain boundary migration make an important contribution to high temperature deformation of polycrystalline materials, particularly for metals. More recently, these processes have been correlated with the atomic structure of the boundaries. Our goal is to study sliding and migration of ice boundaries, with respect to temp...

Grain-boundary melting: A Monte Carlo study.

Grain-boundary-induced melting in quenched polycrystalline monolayers.

Melting in two dimensions can successfully be explained with the Kosterlitz-Thouless-Halperin-Nelson-Young (KTHNY) scenario which describes the formation of the high-symmetry phase with the thermal activation of topological defects within an (ideally) infinite monodomain. With all state variables being well defined, it should hold also as freezing scenario where oppositely charged topological d...